IMPROVED PREPARATION OF (3-BETA,5-ALPHA,14-ALPHA)-3-HYDROXY-14-METHYLCHOLEST-7-EN-15-ONE - SYNTHESIS OF ERGOSTENONE AND 20-ALPHA-(HYDROXYMETHYL)PREGNENONE ANALOGS

被引：30
作者：
DOLLE, RE
KRUSE, LI
机构：
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1986年 / 51卷 / 21期
关键词：
D O I：
10.1021/jo00371a025
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
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页码：4047 / 4053
页数：7
相关论文
共 28 条
[1]   15-OXYGENATED STEROLS BY META-CHLOROPERBENZOIC ACID OXIDATION OF 3-BETA-ACETOXY-5-ALPHA-CHOLESTA-8,14-DIENE [J].
ANASTASIA, M ;
ALLEVI, P ;
FIECCHI, A ;
SCALA, A .
JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (16) :3265-3267
[2]   A NEW ROUTE TO STEROID RING-C AROMATIZATION FROM READILY AVAILABLE PRECURSORS [J].
ANASTASIA, M ;
ALLEVI, P ;
FIECCHI, A ;
SCALA, A .
LIPIDS, 1982, 17 (03) :226-229
[3]   RHODIUM-CATALYZED ISOMERIZATION OF SOME UNSATURATED ORGANIC SUBSTRATES [J].
ANDRIEUX, J ;
BARTON, DHR ;
PATIN, H .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (04) :359-363
[4]   BIOSYNTHESIS OF TERPENES AND STEROIDS .5. SYNTHESIS OF ERGOSTA-5,7,22,24(28)-TETRAEN-3BETA-OL, A BIOSYNTHETIC PRECURSOR OF ERGOSTEROL [J].
BARTON, DHR ;
SHIORI, T ;
WIDDOWSON, DA .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1971, (10) :1968-+
[5]   SOME OXIDATION PRODUCTS OF ERGOSTA-7-14-22-TRIEN-3-BETA-YL ACETATE (ERGOSTEROL-B3 ACETATE) [J].
BARTON, DHR ;
LAWS, GF .
JOURNAL OF THE CHEMICAL SOCIETY, 1954, (JAN) :52-63
[6]  
CRAWFORD TC, 1980, TETRAHEDRON LETT, P697
[7]  
CRAWFORD TC, 1980, TETRAHEDRON LETT, P693
[8]  
FIESER L, 1959, STEROIDS, P111
[9]  
KNIGHT JC, 1966, J BIOL CHEM, V241, P1502
[10]  
LAKEMAN J, 1967, TETRAHEDRON LETT, P3699
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