HOMOLYTIC ALKYLATION OF NAPHTHOQUINONE AND METHYL-NAPHTHOQUINONE - ENTHALPIC, STERIC AND POLAR EFFECTS

被引：29

作者：

COPPA, F ^{[1
]}

FONTANA, F ^{[1
]}

MINISCI, F ^{[1
]}

BARBOSA, MCN ^{[1
]}

VISMARA, E ^{[1
]}

机构：

[1] POLITECN MILAN,DIPARTMENTO CHIM,PIAZZA LEONARDO VINCI 32,I-20133 MILAN,ITALY

来源：

TETRAHEDRON | 1991年 / 47卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(01)89736-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The homolytic methylation of napthoquinone to obtain menadione has been investigated by three sources of methyl radical: t-BuOOH, DMSO and H2O2, acetone and H2O2. Moreover the homolytic alkylation of napthoquinone and 2-methylnapthoquinone has been investigated by using alkyl iodides as sources of alkyl radicals.

引用

页码：7343 / 7352

页数：10

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