SYNTHESIS OF GRAFT-COPOLYMERS OF POLY(CAPROLACTONE) AND POLY(METHYL METHACRYLATE) AND THE USE OF THESE MATERIALS TO SYNTHESIZE SOFT-SEGMENT GRAFTED POLYURETHANES

被引：7

作者：

RIMMER, S ^{[1
]}

GEORGE, MH ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,S KENSINGTON,LONDON SW7 2AY,ENGLAND

来源：

EUROPEAN POLYMER JOURNAL | 1993年 / 29卷 / 2-3期

关键词：

D O I：

10.1016/0014-3057(93)90084-S

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(caprolactone)/poly(methyl methacrylate) graft polyols, P(CL-g-MMA)s, have been synthesized. The synthetic method involved the ring opening polymerization of epsilon-caprolactone, in solution, by initiation with a diol functional macromonomer based on poly(methyl methacrylate) (PMMA). The molecular weight of these materials was determined by end group analysis. The resultant polyols have been used to produce polyurethanes, with PMMA side chains located in the soft-segments, P(U-g-MMA)s. GPC, H-1 and C-13-NMR and FTIR were used to characterize these materials.

引用

页码：205 / 210

页数：6

共 18 条

[1]

ACKELRUD L, 1986, J POLYM SCI, V24, P2831

[2] STUDIES ON FUNCTIONALIZING AND GRAFTING TO POLY(ETHER-URETHANES) [J].

BAMFORD, CH ;

MIDDLETON, IP .

EUROPEAN POLYMER JOURNAL, 1983, 19 (10-1) :1027-1035

[3] DILUTE SOLUTION STUDIES OF NITROGEN-SUBSTITUTED POLYURETHANES [J].

BEACHELL, HC ;

BUCK, JCP .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (7PA1) :1873-&

[4]

BEACHELL HC, 1969, J POLYM SCI C, V22, P569

[5] POLYMER NSR SPECTROSCOPY .2. THE HIGH RESOLUTION SPECTRA OF METHYL METHACRYLATE POLYMERS PREPARED WITH FREE RADICAL AND ANIONIC INITIATORS [J].

BOVEY, FA ;

TIERS, GVD .

JOURNAL OF POLYMER SCIENCE, 1960, 44 (143) :173-182

[6] SYNTHESIS OF POLYURETHANE GRAFT-COPOLYMERS BY POLYADDITION REACTION OF DIHYDROXYL-TERMINATED MACRO-MONOMERS [J].

CHUJO, Y ;

TATSUDA, T ;

YAMASHITA, Y .

POLYMER BULLETIN, 1982, 8 (5-6) :239-244

[7]

KURIYAMA K, 1987, Patent No. 115917

[8]

Kuryla W.C., 1966, J CELL PLAST, V2, P84

[9] LACTONE POLYMERS .3. POLYMERIZATION OF EPSILON-CAPROLACTONE [J].

LUNDBERG, RD ;

KOLESKE, JV ;

WISCHMAN.KB .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (10PA) :2915-&

[10]

MORIMOTO A, 1986, Patent No. 200116

← 1 2 →