MODELING THE VOLTAMMETRIC STUDY OF INTERCALATION IN A HOST STRUCTURE - APPLICATION TO LITHIUM INTERCALATION IN RUO2

被引：54

作者：

ARMAND, M ^{[1
]}

DALARD, F ^{[1
]}

DEROO, D ^{[1
]}

MOULIOM, C ^{[1
]}

机构：

[1] CNRS,ENERGET ELECTROCHEM LAB 265,BP 75,F-38402 ST MARTIN HERES,FRANCE

来源：

SOLID STATE IONICS | 1985年 / 15卷 / 03期

关键词：

ELECTRIC MEASUREMENTS - ELECTROLYTIC CELLS - Materials - LITHIUM COMPOUNDS - Electric Conductivity;

D O I：

10.1016/0167-2738(85)90004-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Intercalation process kinetics have been studied theoretically for the case of potential voltammetry. The influence of the thickness (or the particle radius) of the 'host' material and the potential sweep rate has been determined between the limits of thin film diffusion and semi-infinite diffusion for a reversible process. Experimental data have been obtained with the cell: RuO//2/LiClO//4-PEO (polyethylene oxide)/Li. The theoretical results have been used to calculate the diffusion coefficient of lithium in the 'host' structure RuO//2 at 80 degree C, giving an approximate value of 1. 6 multiplied by 10** minus **1**1 cm**2 s** minus **1.

引用

页码：205 / 210

页数：6

共 19 条

[1]

ARMAND M, 1978, THESIS GRENOBLE

[2]

ARMAND M, 1983, EXTENDED ABSTRACTS, V494, P752

[3]

ARMAND M, 1981, JUI JOURN EL BRUX

[4] DYNAMIC ASPECTS OF SOLID-SOLUTION CATHODES FOR ELECTROCHEMICAL POWER SOURCES [J].

ATLUNG, S ;

WEST, K ;

JACOBSEN, T .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (08) :1311-1321

[5]

BARRAL G, 1982, 33RD M ISE LYON, V2, P750

[6]

BRUMLEVE TR, 1979, J ELECTROANAL CHEM, V90, P1

[7]

CHABAGNO JM, 1980, THESIS GRENOBLE

[8]

DALLARD F, 1983, J POWER SOURCES, V9, P321

[9] THEORY OF IRREVERSIBLE WAVES IN OSCILLOGRAPHIC POLAROGRAPHY [J].

DELAHAY, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (05) :1190-1196

[10]

FOULETIER M, 1983, THESIS GRENOBLE

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