MICROWAVE-ASSISTED LEWIS-ACID CATALYSIS - APPLICATION TO THE SYNTHESIS OF ALKYLHALOGERMANES OR ARYLHALOGERMANES

被引：25

作者：

LAURENT, R

LAPORTERIE, A

DUBAC, J

BERLAN, J

机构：

[1] UNIV TOULOUSE 3,ORGANOMET LAB,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE

[2] ENSIGC,SYNTH ORGAN MILIEUX POLYPHAS LAB,F-31078 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 06期

关键词：

D O I：

10.1021/om00018a050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under microwave irradiation, alkyl- or arylhalogermanes RnGeX4, (R = Et, Bu, Ph; X = Cl, Br) are obtained by redistribution reactions of R4Ge with GeX4. These experimental conditions permit the synthesis of such compounds in good yield in a few minutes at atmospheric pressure. The direct Friedel-Crafts germylation of benzene and toluene by germanium tetrachloride also has been performed, but yields were low.

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页码：2493 / 2495

页数：3

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