THERMAL-DECOMPOSITION AND KINETIC-PARAMETERS OF CHROMIUM(III) AND THORIUM(IV) COMPLEXES WITH ORTHOVANILIN OXIME

被引:0
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作者
DHAR, ML
SINGH, O
MAGAZINE, N
SHARMA, RM
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O6 [化学];
学科分类号
0703 ;
摘要
The use of non-isothermal methods for finding the kinetic parameters (E, Z and DELTA-S*) and the mechanism of decomposition of the complexes, tris(orthovanilinoximate)chromium(III) and tetrakis(orthovanilin-oximate)diaquothorium(IV) is reported. The former complex decomposes regularly without any distinguishable rest in the curve while the latter decomposes with a distinguishable rest in the curve. Both the complexes involve random nucleation mechanism.
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页码:803 / 805
页数:3
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