EFFECT OF PRESSURE ON THE TRANSFORMATION OF METHANOL INTO HYDROCARBONS ON AN AMORPHOUS SILICA-ALUMINA

被引：14

作者：

COMELLI, RA ^{[1
]}

FIGOLI, NS ^{[1
]}

机构：

[1] INCAPE, INST INVEST CATALISIS & PETROQUIM, RA-3000 SANTA FE, ARGENTINA

来源：

APPLIED CATALYSIS | 1991年 / 73卷 / 02期

关键词：

AGING; COKE FORMATION; HYDROCARBONS; METHANOL; PRESSURE EFFECTS; SELECTIVITY (AROMATICS); SILICA-ALUMINA;

D O I：

10.1016/0166-9834(91)85136-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of pressure on the transformation of methanol into hydrocarbons on an amorphous silica-alumina catalyst was studied. The increase in pressure (above atmospheric) produced a sharp increase in the production of hydrocarbons with five or more C atoms (C5+), an increase in the total aromatics selectivity in the C5+ fraction, and a better catalyst stability. Small changes were observed in the selectivity for solid aromatics in the C5+ fraction when pressure increased.

引用

页码：185 / 194

页数：10

共 27 条

[1]

[Anonymous], 1977, [No title captured], Patent No. 4013732

[2]

Argauer R.J., 1972, U.S. Patent, Patent No. [3,702,886, 3702886]

[3]

Chang C.D., 1975, U.S. Patent, Patent No. [3,928,483, 3928483]

[4] HYDROCARBONS FROM METHANOL [J].

CHANG, CD .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1983, 25 (01) :1-118

[5] METHANOL CONVERSION TO LIGHT OLEFINS [J].

CHANG, CD .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1984, 26 (3-4) :323-345

[6] PROCESS STUDIES ON CONVERSION OF METHANOL TO GASOLINE [J].

CHANG, CD ;

KUO, JCW ;

LANG, WH ;

JACOB, SM ;

WISE, JJ ;

SILVESTRI, AJ .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1978, 17 (03) :255-260

[7] CONVERSION OF METHANOL AND OTHER O-COMPOUNDS TO HYDROCARBONS OVER ZEOLITE CATALYSTS .2. PRESSURE EFFECTS [J].

CHANG, CD ;

LANG, WH ;

SMITH, RL .

JOURNAL OF CATALYSIS, 1979, 56 (02) :169-173

[8] CONVERSION OF METHANOL AND OTHER O-COMPOUNDS TO HYDROCARBONS OVER ZEOLITE CATALYSTS [J].

CHANG, CD ;

SILVESTRI, AJ .

JOURNAL OF CATALYSIS, 1977, 47 (02) :249-259

[9] METHANOL CONVERSION TO OLEFINS OVER ZSM-5 .1. EFFECT OF TEMPERATURE AND ZEOLITE SIO2/AL2O3 [J].

CHANG, CD ;

CHU, CTW ;

SOCHA, RF .

JOURNAL OF CATALYSIS, 1984, 86 (02) :289-296

[10]

CHANG CD, 1975, Patent No. 3894106

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