TEMPERATURE AND CONCENTRATION-DEPENDENCE OF ELECTRICAL CONDUCTANCE OF A MIXTURE OF SODIUM AND POTASSIUM THIOCYANATES IN AQUEOUS-MEDIUM

被引：4

作者：

GUPTA, RL ^{[1
]}

ISMAIL, K ^{[1
]}

机构：

[1] NE HILL UNIV,DEPT CHEM,BIJNI COMPLEX,SHILLONG 793003,MEGHALAYA,INDIA

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1991年 / 36卷 / 02期

关键词：

D O I：

10.1021/je00002a004

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Molar conductance and density of the [xNaSCN + (1 - x)KSCN] + RH2O system were measured as functions of x, R, and temperature (283-323 K). Deviation of molar conductance from additivity occurs at all the temperatures in the region R less-than-or-equal-to 10. The amount of this deviation is found to be independent of temperature. The isothermal concentration dependence of molar conductance was described by the expression LAMBDA = LAMBDA-FLK exp(Bc + Cc2), where LAMBDA-FLK is the Falkenhagen-Leist-Kelbg equation for LAMBDA. B and C are empirical constants, and c is the molar concentration. The temperature dependence of LAMBDA has been described by the Vogel-Tammann-Fulcher equation.

引用

页码：142 / 147

页数：6

共 6 条

[1]

Claes P., 1981, IONIC LIQUIDS, P291, DOI 10.1007/978-1-4757-0920-9_14

[2]

FALKENHAGEN H, 1952, ANN PHYSIK, V6, P51

[3] ELECTRICAL CONDUCTANCE OF A MIXTURE OF SODIUM AND POTASSIUM THIOCYANATES IN AQUEOUS-MEDIUM AT 25-DEGREES-C [J].

GUPTA, RL ;

ISMAIL, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (07) :2605-2608

[4]

HORVATH AL, 1985, HDB AQUEOUS ELECTROL, P262

[5]

WEAST RC, 1977, HDB CHEM PHYSICS

[6] THE DIFFUSION COEFFICIENTS AND CONDUCTANCES OF SOME CONCENTRATED ELECTROLYTE SOLUTIONS AT 25-DEGREES [J].

WISHAW, BF ;

STOKES, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (08) :2065-2071

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