STUDIES ON TRANSITION-METAL NITRIDO AND OXO COMPLEXES .15. OXO COMPLEXES OF RUTHENIUM WITH N,N'-DONORS AS OXIDATION CATALYSTS FOR ALKENES, ALKANES ALCOHOLS, AND THEIR OSMIUM ANALOGS

被引：28

作者：

BAILEY, AJ

GRIFFITH, WP

SAVAGE, PD

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] SHELL RES LTD,THORNTON RES CTR,DEPT LUBRICAT & SPECIAL PROD,CHESTER CH1 3SH,CHESHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 21期

关键词：

D O I：

10.1039/dt9950003537

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Catalysis of the epoxidation of alkenes and oxidation of alkanes acid alcohols by a variety of bis-bipy (2,2'-bipyridyl) and bis-phen (1,10-phenanthroline) ruthenium complexes with NalO(4) or [NBu(4)]IO4 as co-oxidants has been investigated together with similar oxidations with [RuO2(bipy){IO3(OH)(3)}]. 1.5H(2)O. The new complexes [RuO2(bipy){TeO2(OH)(4)}] and [OsO2(L-L){IO3(OH)(3)}] (L-L = bipy, phen or 2,2'-dipyridylamine) have been prepared and characterised.

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页码：3537 / 3542

页数：6

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