PHOSPHORUS PENTOXIDE AT 233 K

被引：61

作者：

STACHEL, D ^{[1
]}

SVOBODA, I ^{[1
]}

FUESS, H ^{[1
]}

机构：

[1] TH DARMSTADT,FB MAT WISSENSCH,D-64287 DARMSTADT,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194012126

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

structure of the thermodynamically most stable form of phosphorus pentoxide, o'(P2O5)(infinity), consists of infinite layers built from six-membered rings of three-corner linked PO4- tetrahedra, as described in 1964 by Cruickshank [Acta Cryst. (1964), 17, 679-680]. The P-O bond distances and P-O-P bond angles reported here differ from Cruickshank's values and show a better agreement with the average ranges of known crystalline phosphate structures.

引用

页码：1049 / 1050

页数：2