CATALYTIC CONVERSION OF ALKENES INTO ALLYLIC ETHERS AND ESTERS USING DISELENIDES HAVING INTERNAL TERTIARY-AMINES

被引：67

作者：

IWAOKA, M ^{[1
]}

TOMODA, S ^{[1
]}

机构：

[1] UNIV TOKYO,COLL ARTS & SCI,DEPT CHEM,MEGURO KU,TOKYO 153,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,2'-Diselenobis {N,N-di[2-(2-pyridyl)ethyl]benzylamine} 1 with copper(II) nitrate or 2,2'-diselenobis(N-cyclohexyl-N-methylbenzylamine) 2 catalyses the conversion of alkenes 3 into oxygenated allylic compounds 4 both in methanol and in acetic acid in the presence of sodium persulfate as an oxidizing agent.

引用

页码：1165 / 1167

页数：3

共 10 条

[1]

BARTON DH, 1981, J CHEM SOC P1, P1947

[2] SOME AMINOETHYLPIPERIDINES AND -PYRIDINES [J].

BRADY, LE ;

FREIFELDER, M ;

STONE, GR .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (11) :4757-&

[3] MODERN ORGANOSELENIUM CHEMISTRY [J].

CLIVE, DLJ .

TETRAHEDRON, 1978, 34 (08) :1049-1132

[4] DIRECT OBSERVATION OF INTRAMOLECULAR INTERACTION BETWEEN A DIVALENT SELENIUM AND A TERTIARY AMINE BY MEANS OF SINGLE-CRYSTAL X-RAY-ANALYSIS AND NMR-SPECTROSCOPY [J].

IWAOKA, M ;

TOMODA, S .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 67 (1-4) :125-130

[5] NEW ORGANOSELENIUM METHODOLOGY [J].

LIOTTA, D .

ACCOUNTS OF CHEMICAL RESEARCH, 1984, 17 (01) :28-34

[6]

Nicolaou K.C., 1984, SELENIUM NATURAL PRO

[7]

PAULMIER C, 1986, SELENIUM REAGENTS IN

[8] FUNCTIONAL-GROUP MANIPULATION USING ORGANOSELENIUM REAGENTS [J].

REICH, HJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (01) :22-30

[9] ELECTROPHILIC ORGANOSELENIUM REAGENTS - NEW ROUTE TO ALLYLIC ACETATES AND ETHERS [J].

SHARPLESS, KB ;

LAUER, RF .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (03) :429-430

[10] GENERATION AND RECYCLE USE OF SELENENYLATING REAGENTS IN ELECTROCHEMICAL OXYSELENENYLATION-DESELENENYLATION OF OLEFINS [J].

TORII, S ;

UNEYAMA, K ;

ONO, M ;

BANNOU, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (15) :4606-4608

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