MOLECULAR-DYNAMICS AND VIBRATIONAL-RELAXATION OF NU-4 MODE IN METHYLCYANIDE

被引：6

作者：

CATALIOTTI, RS ^{[1
]}

MARIANI, L ^{[1
]}

MORRESI, A ^{[1
]}

PALIANI, G ^{[1
]}

GIORGINI, MG ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM FIS & INORGAN,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 293卷

关键词：

D O I：

10.1016/0022-2860(93)80054-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman vibrational bandshape of the nu4 mode of methylcyanide has been studied as a function of temperature in both CH3CN and CD3CN isotopomers. The secondary structure of such bands in these molecules has been interpreted and analyzed as a sequence of hot bands: spectral fittings and a suitable vibrational relaxation mechanism are proposed.

引用

页码：223 / 226

页数：4

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