PHOTOELECTROCHEMICAL DECOMPOSITION OF SURFACTANTS ON A TIO2/TCO PARTICULATE FILM ELECTRODE ASSEMBLY

被引：75
作者：
HIDAKA, H
ASAI, Y
ZHAO, JC
NOHARA, K
PELIZZETTI, E
SERPONE, N
机构：
[1] UNIV TURIN, DIPARTIMENTO CHIM ANALIT, I-10125 TURIN, ITALY
[2] CONCORDIA UNIV, DEPT CHEM, PURE & APPL STUDIES CATALYSIS ENVIRONM & MAT LAB, MONTREAL, PQ H3G 1M8, CANADA
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 20期
关键词：
D O I：
10.1021/j100020a056
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photooxidative degradation of an anionic surfactant, sodium dodecylbenzene sulfonate (DBS), has been examined on a TiO2 thin film immobilized onto a transparent semiconducting oxide (TCO support) electrode assembly. Some of the characteristics of this assembly have been explored. Changes in the rates of decomposition as a function of applied bias and as a function of the nature of the supporting electrolyte were surveyed. The efficiency of the photodegradation was governed by the electrode potential.
引用
收藏
页码：8244 / 8248
页数：5
相关论文
共 20 条
[1]  
[Anonymous], 1993, P 1 INT C TIO2 PHOT
[2]  
BAHNEMANN D, 1994, AQUATIC AND SURFACE PHOTOCHEMISTRY, P261
[3]   ELECTROCHEMICAL REACTIONS INVOLVING HOLES AT ILLUMINATED TIO2 (RUTILE) SINGLE-CRYSTAL ELECTRODE [J].
DUTOIT, EC ;
CARDON, F ;
GOMES, WP .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1976, 80 (12) :1285-1288
[4]  
FRINKLEA HO, 1988, SEMICONDUCTOR ELECTR, P1
[5]  
HIDAKA H, 1994, NEW J CHEM, V18, P541
[6]   PHOTODEGRADATION OF SURFACTANTS .9. THE PHOTOCATALYZED OXIDATION OF POLYOXYETHYLENE ALKYL ETHER HOMOLOGS AT TIO2 WATER INTERFACES [J].
HIDAKA, H ;
ZHAO, JC ;
KITAMURA, K ;
NOHARA, K ;
SERPONE, N ;
PELIZZETTI, E .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1992, 64 (01) :103-113
[7]   PHOTODEGRADATION OF SURFACTANTS .8. COMPARISON OF PHOTOCATALYTIC PROCESSES BETWEEN ANIONIC SODIUM DODECYLBENZENESULFONATE AND CATIONIC BENZYLDODECYLDIMETHYLAMMONIUM CHLORIDE ON THE TIO2 SURFACE [J].
HIDAKA, H ;
ZHAO, J ;
PELIZZETTI, E ;
SERPONE, N .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (05) :2226-2230
[8]   PHOTODEGRADATION OF SURFACTANTS .12. PHOTOCATALYZED MINERALIZATION OF PHOSPHORUS-CONTAINING SURFACTANTS AT TIO2/H2O INTERFACES [J].
HIDAKA, H ;
ZHAO, JC ;
SATOH, Y ;
NOHARA, K ;
PELIZZETTI, E ;
SERPONE, N .
JOURNAL OF MOLECULAR CATALYSIS, 1994, 88 (02) :239-248
[9]   PHOTODEGRADATION OF SURFACTANTS CATALYZED BY A TIO2 SEMICONDUCTOR [J].
HIDAKA, H ;
ZHAO, J .
COLLOIDS AND SURFACES, 1992, 67 :165-182
[10]  
HIDAKA H, 1993, TR MET ENV, V3, P251
12