KINETICALLY STABLE ADDUCT OF SAMAROCENE WITH ALUMINUM DEUTERIDE (ETA-C5H3TBU2)2SM(MU-2-D)2ALD.ME2NC2H4NME2

被引：10
作者：
GUNKO, YK
BULYCHEV, BM
BELSKY, VK
SOLOVEICHIK, GL
机构：
[1] LY KARPOV PHYS CHEM RES INST,MOSCOW 103064,USSR
[2] RUSSIAN ACAD SCI,INST CHEM PHYS CHERNOGOLOVKA,CHERNOGOLOVKA 142432,USSR
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 440卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(92)83483-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The interaction of (C5H3tBu2)2Sm.THF with AlD3 in ether in the presence of TMEDA yields compounds of composition (C5H3tBu2)2SmAlD3.TMEDA (I). Metal atoms are bonded by the double bridge SmD2Al. The coordination polyhedron of Al in I is a trigonal bipyramid. Stability of this substance to redox reaction occurring in the Cp2"Sm.THF-AlD3 system can be explained by the isotopic kinetic effect.
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页码：47 / 52
页数：6
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