CONVENIENT PREPARATIONS OF THE MIXED 1,3,2,4-/1,2,3,5-DITHIADIAZOLYLIUM SALT [SNSNC-C6H4-CNSSN][ASF6]2 AND THE 1ST MIXED FREE-RADICAL, PARA-[SNSNC-C6H4-CNSSN]2-BULLET

被引：8
作者：
BANISTER, AJ [1 ]
LAVENDER, I [1 ]
RAWSON, JM [1 ]
WHITEHEAD, RJ [1 ]
机构：
[1] UNIV DURHAM,DEPT PHYS,DURHAM DH1 3LE,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 08期
关键词：
D O I：
10.1039/dt9920001449
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The salt [p-NCC6H4- activated -CNSSN] Cl {prepared by reaction of Li[p-NCC6H4C(NSiMe3)2] with SCl2} was converted into [p-NCC6H4- activated -CNSSN]Asf6 (with AgAsF6) and then reacted with [SNS]AsF6 to provide [activated SNSNC-C6H4- activated CNSSN][AsF6]2 in 92% recovered yield. Complete reduction of this material produced the first mixed 1,3,2,4-/1,2,3,5-dithiadiazole diradical, [activated SNSNC-C6H4- activated CNSSN]2..
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页码：1449 / 1450
页数：2
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