MOLECULAR AND CRYSTAL-STRUCTURE OF MAGNESIUM BIS[BIS(TRIMETHYLSILYL)PHOSPHIDE].DME

被引：20

作者：

WESTERHAUSEN, M

SCHWARZ, W

机构：

[1] Institut Für Anorganische Chemie, Universität Stuttgart, D-70569

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 02期

关键词：

MAGNESIUM BIS[BIS(TRIMETHYLSILYL)PHOSPHIDE].DME; PHOSPHIDE; X-RAY STRUCTURE;

D O I：

10.1002/zaac.19946200215

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Magnesium bis[bis(trimethylsilyl)phosphide] crystallizes in the tetragonal space group I4c2BAR with a = 1652.9(2); c = 2 282.6(5) pm and Z = 8. The magnesium atom is distorted tetrahedrally surrounded by two oxygen and two phosphorus atoms with Mg-P- and Mg-0-bond lengths of 248.7(2) and 204.7(5) pm, respectively. The phosphorus atom displays a trigonal pyramidal coordination.

引用

页码：304 / 308

页数：5

共 25 条

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