HYDROGENATION OF BUCKMINSTERFULLERENE C-60 VIA HYDROZIRCONATION - A NEW WAY TO ORGANOFULLERENES

被引：102

作者：

BALLENWEG, S

GLEITER, R

KRATSCHMER, W

机构：

[1] MAX PLANCK INST NUCL PHYS,POSTFACH 103980,W-6900 HEIDELBERG 1,GERMANY

[2] UNIV HEIDELBERG,INST ORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(00)79214-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogenation of buckminsterfullerene C60 has been achieved via reaction with (eta5-C5H5)2Zr(H)Cl (hydrozirconation). Hydrolysis of the intermediate C60 zirconium(IV) complex, [(eta5-C5H5)2ZrCl]nC60Hn with n=1,2,3 yielded a mixture of C60H2n and unreacted C60, from which C60H2 has been isolated through preparative high performance liquid chromatography (HPLC).

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页码：3737 / 3740

页数：4

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