SYNTHESIS OF SUBSTITUTED ALPHA-METHYLENE LACTAMS BY RHODIUM-CATALYZED CARBONYLATION OF ACETYLENIC AMINES

被引：24

作者：

CAMPI, EM

CHONG, JM

JACKSON, WR

VANDERSCHOOT, M

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ON,CANADA

来源：

TETRAHEDRON | 1994年 / 50卷 / 08期

关键词：

D O I：

10.1016/S0040-4020(01)86969-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of gamma- and beta-aminoalkynes, (2) and (5) with hydrogen and carbon monoxide in the presence of rhodium catalysts give substituted alpha-methylene-2-piperidinones (7) and 2-pyrrolidinones (11).

引用

页码：2533 / 2542

页数：10

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