RECOIL CHLORINE REACTIONS WITH ETHYLENE

被引：4

作者：

CHAO, JH ^{[1
]}

LO, JG ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,INST NUCL SCI,HSINCHU 30043,TAIWAN

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1994年 / 185卷 / 02期

关键词：

D O I：

10.1007/BF02041308

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The reactions of re:coil Cl-38 atoms produced through the Cl-37(n, gamma)Cl-38 process in the CF3Cl-C2H4 gas phase are described in this work, The CF3Cl is a chlorine source as well as moderator. Scavengers, such as O-2 and H2S, were added to the system to discriminate the reactions induced by energetic and/or thermal chlorine atoms. The radioactive Cl-38-labeled products were separated using gas-chromatographic technique followed by an external proportional counter for quantitative determination of the product yields. The mechanisms of the chemical reactions are predicted to account for the formation of these organic compounds.

引用

页码：355 / 367

页数：13

共 9 条

[1]

KIKUCHI M, 1985, J PHYS CHEM-US, V85, P84

[2]

LEE FSC, 1977, J PHYS CHEM-US, V81, P1222, DOI 10.1021/j100528a002

[3] THERMAL CL-38 ATOM REACTIONS WITH ETHYLENE/YLE [J].