A CONVENIENT SYNTHESIS OF MASKED BETA-KETOALDEHYDES BY THE CONTROLLED ADDITION OF NUCLEOPHILES TO (TRIMETHYLSILYL)ETHYNYL KETONES

被引：18

作者：

BROMIDGE, SM ^{[1
]}

ENTWISTLE, DA ^{[1
]}

GOLDSTEIN, J ^{[1
]}

ORLEK, BS ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,LONDON SW7 2AZ,ENGLAND

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 04期

关键词：

D O I：

10.1080/00397919308009803

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The controlled addition of nucleophiles to (trimethylsilyl)ethynyl ketones provides a facile route to beta-ketoacetals, beta-alkoxy-alpha,beta-unsaturated ketones or vinylogous amides depending on the choice of reaction conditions.

引用

页码：487 / 494

页数：8

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