SYNTHESIS, CRYSTAL-STRUCTURE AND PROPERTIES OF A 5-COORDINATE COPPER(II) COMPLEX

被引：6

作者：

JIANG, ZH ^{[1
]}

BAI, LG ^{[1
]}

LIAO, DZ ^{[1
]}

HUANG, JH ^{[1
]}

WANG, GL ^{[1
]}

WANG, HG ^{[1
]}

YAO, XK ^{[1
]}

机构：

[1] NANKAI UNIV,CENT LAB,TIANJIN,PEOPLES R CHINA

来源：

POLYHEDRON | 1993年 / 12卷 / 05期

关键词：

D O I：

10.1016/S0277-5387(00)83404-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The five-coordinate copper(II) complex [(3,3'-trimethylenedinitrilo)bis(2-butanone oximato)]copper(II) bromide (CuHLBr) has been prepared and its crystal structure has been determined. The complex has a square-pyramidal structure with the copper displaced 0.43 angstrom out of the basal nitrogen plane. The Cu-Br distance is 2.955 angstrom. The differences in the structures of the copper(II) and copper(I) complexes is discussed. Covalency of the coordinate bond for the title complex is also discussed based on ESR spectra.

引用

页码：523 / 525

页数：3

共 7 条

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