CONTROL OF CDW STATE IN HALOGEN-BRIDGED METAL-COMPLEXES

被引：78
|
作者：
OKAMOTO, H
MITANI, T
TORIUMI, K
YAMASHITA, M
机构：
[1] HIMEJI INST TECHNOL,DEPT MAT SCI,OSAKA 67812,JAPAN
[2] NAGOYA UNIV,COLL GEN EDUC,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN
来源：
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 1992年 / 13卷 / 04期
关键词：
D O I：
10.1016/0921-5107(92)90140-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Chemical modifications of one-dimensional (1D) halogen-bridged mixed-valence metal complexes have been made in order to control the amplitude of the charge density wave (CDW) state in -M-X- chains (M=Pt, Pd or Ni, and X=Cl, Br or I). By changing chemical parameters, such as strength of hydrogen-bonds between the ligands and the counter anions, and the ionic radii of M and X, the characteristic diagram of the amplitude of CDW has been obtained as a function of the M-X-M distances. This provides a new basic idea for understanding the 1D electronic state of the M-X compounds, especially as related to dynamical phenomena originated in the charge transfer instability in the ground state and the photo-excited state.
引用
收藏
页码：L9 / L14
页数：6
相关论文
共 50 条
  • [31] SPECTROSCOPIC STUDY ON THE HALOGEN-MIXED CRYSTALS OF HALOGEN-BRIDGED PLATINUM COMPLEXES
    TANAKA, M
    KURITA, S
    HARUKI, M
    FUJISAWA, M
    SYNTHETIC METALS, 1987, 21 (01) : 103 - 108
  • [32] SYNTHESIS OF CYCLOMETALLATED HALOGEN-BRIDGED BINUCLEAR COMPLEXES OF PALLADIUM AND PLATINUM
    ABICHT, HP
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (1-2) : 57 - 61
  • [33] ANTIFERROMAGNETIC BINUCLEAR HALOGEN-BRIDGED DITHIOCARBAMATE COMPLEXES OF COPPER(II)
    FURNEAUX, RH
    SINN, E
    INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1976, 12 (06): : 501 - 503
  • [34] MECHANISM OF CLEAVAGE OF HALOGEN-BRIDGED RHENIUM CARBONYL NITROSYL COMPLEXES
    ZINGALES, F
    TROVATI, A
    UGUAGLIA.P
    INORGANIC CHEMISTRY, 1971, 10 (03) : 510 - &
  • [35] Multichanneled relaxation of halogen-bridged diplatinum chain complexes photoexcited
    Yamamoto, Shoji
    Ohara, Jun
    PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 6, NO 1, 2009, 6 (01): : 144 - 148
  • [36] STRUCTURAL CONTROL OF QUASI-ONE-DIMENSIONAL HALOGEN-BRIDGED NICKEL-COMPLEXES
    INOUE, K
    YAMASHITA, M
    FURUTA, T
    ICHIKAWA, A
    OHISHI, T
    OKAMOTO, H
    KIMURA, N
    OHKI, H
    IKEDA, R
    BANDOW, S
    TORIUMI, K
    MITANI, T
    KITAGAWA, H
    MIYAMAE, H
    SYNTHETIC METALS, 1995, 71 (1-3) : 1913 - 1914
  • [37] THE REACTION OF BINUCLEAR HALOGEN-BRIDGED COMPLEXES OF PLATINUM(II) WITH MONOAMINES
    CHATT, J
    VENANZI, LM
    JOURNAL OF THE CHEMICAL SOCIETY, 1955, : 3858 - 3864
  • [38] ESR studies of quasi-one-dimensional halogen-bridged mixed-metal complexes
    Tanaka, H
    Marumoto, K
    Kuroda, S
    Manabe, T
    Furukawa, S
    Yamashita, M
    EPR IN THE 21ST CENTURY: BASICS AND APPLICATIONS TO MATERIAL, LIFE AND EARTH SCIENCES, 2002, : 79 - 84
  • [39] PREPARATION OF HALOGEN-BRIDGED CATIONIC DINUCLEAR COMPLEXES OF MANGANESE AND RHENIUM
    MEWS, R
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (01): : 56 - 56
  • [40] A 2 BAND MODEL FOR HALOGEN-BRIDGED TRANSITION-METAL LINEAR-CHAIN COMPLEXES
    BISHOP, AR
    GAMMEL, JT
    LOH, EY
    PHILLPOT, SR
    WEBERMILBRODT, SM
    INTERACTING ELECTRONS IN REDUCED DIMENSIONS, 1989, 213 : 267 - 272
12345