Annihilation of singlet excited states in anthracene solutions

被引:0
|
作者
Babenko, S. D. [1 ]
Benderskii, V. A. [1 ]
Gol'danskii, V. L. [1 ]
Lavrushko, A. G. [1 ]
Tychinskii, V. P. [1 ]
机构
[1] Acad Sci, Inst Chem Phys, Moscow, Russia
关键词
D O I
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The quenching of anthracene fluorescence in benzene solutions under high UV light intensity has been studied using a pulsed nitrogen laser (lambda= 3371 angstrom. It is shown to result from singlet-singlet and singlet-triplet annihilation. The overall annihilation rate constant is (3.5 +/- 1.5) x 10(-10) cm(-3) sec(-1). Annihilation is due to dipole-dipole interaction of excited molecules.
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页码:598 / 600
页数:3
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