Kinetic trends have been identified for mass transport of molten metals into sintered TiC−(Ni, Mo) hard alloys. Conditions have been identified for the mass transfer of the liquid by the migration and diffusion-migration mechanisms. Details are given of the formation of gradient structure in the TiC−(Ni, Mo) hard alloys on interaction with molten metals, where it is found that there are effects from the physicomechanical properties of the materials.