A three-dimensional porous and magnetic framework constructed from copper salt and 5-Methyltetrazole: [Cu8(Metz)9](OH)·xH2O

被引：0
作者：
Dong-Sheng Liu
Ji-Wei Wang
Li-Ming Zhang
Wen-Tong Chen
Jian-Gen Huang
Yan Sui
机构：
[1] Jinggangshan University,Institute of Applied Chemistry, School of Chemistry and Chemical Engineering
来源：
Journal of the Iranian Chemical Society | 2014年 / 11卷
关键词：
Cu; complex; 5-Methyltetrazole; Adsorption; Magnetic properties;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new compound of [Cu8(Metz)9](OH)·xH2O (x≈3) (1) (Metz = 5-Methyltetrazole) has been prepared and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal is of hexagonal, space group P63/m with a = b = 13.988(1) Å, c = 16.309(2) Å, α = β = 90°, γ = 120°, V = 2 763.5 (4) Å3, Mr = 1327.13, Dc = 1.595 g cm−3, Z = 2, F(000) = 1 316, μ = 3.076 mm−1, the final R = 0.0494 and wR = 0.1532 for 1,731 observed reflections (I > 2σ(I)). In this compound, the [(CuII)2(CuI)6(Metz)9]+ cationic clusters are connected together through CuI cations and Metz ligands and result in a three-dimensional framework. Remarkable, three-dimensional intersecting channels exist in it. The variable temperature magnetic investigations indicate that 1 exhibits typical antiferromagnetic behaviors. N2 gas adsorption measurements at 77 K showed that compound 1 possesses permanent porosities.
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页码：847 / 852
页数：5
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