Molecular Interaction and Physico-Chemical Analysis in Ternary Organic Molecules (Toluene plus Chloroform plus Cyclohexane) at Various Temperatures

被引:2
作者
Nithiyanantham, S. [1 ,2 ]
Vanathi, V. [3 ]
Mullainathan, S. [1 ,2 ]
Mahalakshmi, S. [4 ]
Palaniappan, L. [5 ]
机构
[1] Thiru Vi Ka Govt Arts Coll, Post Grad & Res Dept Phys, Ultrason Div, Thiruvarur 610003, India
[2] Thiru Vi Ka Govt Arts Coll, Post Grad & Res Dept Phys, Bio Phys Div, Thiruvarur 610003, India
[3] AVC Coll Engn, Dept Phys, Mayiladuthurai 609309, Tamil Nadu, India
[4] Ethiraj Coll Women, Post Grad & Res Dept Phys, Chennai 600008, Tamil Nadu, India
[5] Annamalai Univ, Dept Phys, Chidambaram 602008, Tamil Nadu, India
来源
CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY | 2022年 / 5卷 / 04期
关键词
Organic mixture; Molecular interaction; Physical parameter; Ideality; Enthalpy; Theory; Model; CHARGE-TRANSFER COMPLEXES; BINARY-LIQUID MIXTURES; REFRACTIVE-INDEXES; SOUND-VELOCITY; ULTRASONIC VELOCITY; VISCOSITIES; TETRAHYDROFURAN; HYDROCARBONS; DENSITIES; CHLORIDE;
D O I
10.1007/s42250-022-00377-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thermo-dynamical analyses towards the organic mixtures are necessary in all industry. The ultrasonic sound velocity (U), measurements in ternary organic mixtures (Toluene + Chloroform + Cyclohexane) have been carried out at 303.15 to 313.15 K. The experimental/derived datas used to compute the deviations for their excess values to investigate and confirming the type of interactions. With this derived parameters to get excess parameters calculated and used to further reconfirming the type, strength, magnitude and further possible interactions such as complex formation, dipole-dipole and dispersions types are interpreted and discussed. In addition the ideal and non-ideal behavior is also analyzed. The Ultrasonic velocity data are with some recent and familiar models and a comparative study of the above models is made to ensure the possible type of interactions among the mixtures.
引用
收藏
页码:849 / 854
页数:6
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