Electrocatalyst engineering and structure-activity relationship in hydrogen evolution reaction: From nanostructures to single atoms析氢反应中电催化剂设计与构效关系: 从纳米结构到单原子

被引:0
作者
Yuan Pan
Chao Zhang
Yan Lin
Zhi Liu
Minmin Wang
Chen Chen
机构
[1] China University of Petroleum (East China),State Key Laboratory of Heavy Oil Processing
[2] Tsinghua University,Department of Chemistry
[3] China University of Petroleum (East China),College of Science
来源
Science China Materials | 2020年 / 63卷
关键词
electrocatalyst; structure-activity relationship; hydrogen evolution reaction; nanomaterials; single-atom site catalysts;
D O I
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中图分类号
学科分类号
摘要
With the ever-pressing issues of global energy demand and environmental pollution, molecular hydrogen has been receiving increasing attention as a clean alternative energy carrier. For hydrogen production, the design and development of high-performance catalysts remains rather challenging. As the compositions and structures of catalyst interfaces have paramount influences on the catalytic performances, the central topic here has always been to design and engineer the interface structures via rational routes so as to boost the activities and stabilities of electrocatalysts on hydrogen evolution reaction (HER). Here in this review, we focus on the design and preparation of multi-scale catalysts specifically catering to HER applications. We start from the design and structure-activity relationship of catalytic nanostructures, summarize the research progresses related to HER nanocatalysts, and interpret their high activities from the atomistic perspective; then, we review the studies regarding the design, preparation, HER applications and structure-activity relationship of single-atom site catalysts (SASCs), and thereupon discuss the future directions in designing HER-oriented SASCs. At the end of this review, we present an outlook on the development trends and faced challenges of catalysts for electrochemical HER.
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页码:921 / 948
页数:27
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[51]  
Zhuang Z(2015)P nanosheet arrays as bifunctional catalysts for overall water splitting Adv Funct Mater 25 1127-1347
[52]  
Yang T T(2015)The Fe-promoted MoP catalyst with high activity for water splitting Adv Mater 27 4234-969
[53]  
Zhu H(1977)Mechanistic insights on ternary Ni I. J Electroanal Chem Interfacial Electrochem 81 97-643
[54]  
Wan M(2005)- J Am Chem Soc 127 5308-53
[55]  
Zhang Z(2007)Co Science 317 100-5129
[56]  
Liu G(2016)P for hydrogen evolution and their hybrids with gra-phene as highly efficient and robust catalysts for overall water splitting Nano Res 9 2079-16638
[57]  
Cui X(2013)Transition metal-doped nickel phosphide nanoparticles as electro- and photocatalysts for hydrogen generation reactions Nano Lett 13 1341-1492
[58]  
Oh A(2012)Defective MoS Nat Mater 11 963-4900
[59]  
Sa Y J(2018) electrocatalyst for highly efficient hydrogen evolution through a simple ball-milling method Nano Energy 49 634-13164
[60]  
Hwang H(2016)Bioinspired iron sulfide nanoparticles for cheap and long-lived electrocatalytic molecular hydrogen evolution in neutral water Nat Mater 15 48-19710