Palladium carboxylate π-complexes with unsaturated hydrocarbons and the reactions catalyzed by them

被引：4

作者：

Shishilov, O. N. ^{[1
]}

Durakov, S. A. ^{[1
]}

Akhmadullina, N. S. ^{[2
]}

Flid, V. R. ^{[1
]}

机构：

[1] MIREA Russian Technol Univ, M V Lomonosov Inst Fine Chem Technol, 86 Prosp Vernadskogo, Moscow 119571, Russia

[2] Russian Acad Sci, A A Baikov Inst Met & Mat Sci, Leninsky Prosp 49, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2024年 / 73卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

palladium; complexes; catalysts; alkenes; allyls; alkynes; arenes; X-RAY-STRUCTURE; C-H ACTIVATION; CROSS-COUPLING REACTIONS; MECHANISTIC INSIGHT; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; HYDRIDE TRANSFER; NORBORNADIENE; ALLYLATION; ARENES;

D O I：

10.1007/s11172-024-4139-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review summarizes the studies on the palladium carboxylate pi-complexes with unsaturated hydrocarbons (alkenes, alkynes, and arenes) as well as with N-heterocyclic carbenes, phosphonyl-substituted ferrocene ligands, etc. In these complexes the palladium atoms are coordinated with unsaturated hydrocarbons via the carbon atoms forming the multiple bonds. These complexes are traditional objects in fundamental coordination chemistry including chemistry of polynuclear compounds. They are also applied as pre-catalysts and as model intermediates for catalytic transformations of unsaturated hydrocarbons, e.g., oxidation and isomerization of alkenes, hydrogenation and coupling reactions of alkenes, alkynes, and arenes.

引用

页码：297 / 327

页数：31

共 88 条

[81] Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates [J].