New Layered Polymer [{Mn(H2O)3}2{Re6Se8(CN)6}] · 3.3H2O: Synthesis and Properties

被引：0
作者：
N. G. Naumov
S. B. Artemkina
A. V. Virovets
V. E. Fedorov
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
来源：
Russian Journal of Coordination Chemistry | 2004年 / 30卷
关键词：
Nitrogen; Polymer; Physical Chemistry; Aqueous Solution; Evaporation;
D O I：
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学科分类号：
摘要：
The [{Mn(H2O)3}2{Re6Se8(CN)6}] · 3.3H2O complex was produced on slow evaporation of an aqueous solution containing the salt of a cluster complex K4Re6Se8(CN)6 · 3.5H2O and a 23-fold excess of Mn2+. The cluster complexes [Re6Se8(CN)6]4– are linked in a crystal into the charged coordination layers [{Mn(H2O)3}4{Re6Se8(CN)6}3]4–2∞ through the Mn2+ cations. The Mn2+ cations are coordinated in a layer by three cyano nitrogen atoms of the cluster complexes; the Mn–N bond lengths are 2.13(4) and 2.21(2) Å. Each [Re6Se8(CN)6]4– anion is bonded to three manganese cations Mn(1). The anions are bonded additionally to the Mn(2) cations disordered over two close positions.
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页码：792 / 799
页数：7
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共 36 条
  • [1] Mironov Y.(1995)undefined Polyhedron 14 3171-undefined
  • [2] Virovets A.V.(1995)undefined Croat. Chem. Acta 68 885-undefined
  • [3] Fedorov V.E.(1997)undefined Zh. Strukt. Khim. 38 1018-undefined
  • [4] Slougui A.(1999)undefined Ukr. Khim. Zh. 65 21-undefined
  • [5] Mironov Y.(1998)undefined Angew. Chem., Int. Ed. Engl. 37 1943-undefined
  • [6] Perrin A.(2000)undefined J. Solid State Chem. 153 195-undefined
  • [7] Fedorov V.E.(1999)undefined Inorg. Chem. 38 1648-undefined
  • [8] Naumov N.G.(2000)undefined J. Am. Chem. Soc. 122 2763-undefined
  • [9] Virovets A.V.(2001)undefined J. Am. Chem. Soc. 123 8022-undefined
  • [10] Podberezskaya N.V.(1991)undefined Eur. J. Solid State Chem. 28 919-undefined
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