Syntheses and Characterization of 2D and 3D Organotin Polymers with Phenylsuccinic Acid and Trimethyltin Chloride Under Different Conditions

被引：0
作者：
Rufen Zhang
Yun Ren
Qingfeng Wang
Chunlin Ma
机构：
[1] Liaocheng University,Department of Chemistry
[2] Taishan University,undefined
来源：
Journal of Inorganic and Organometallic Polymers and Materials | 2010年 / 20卷
关键词：
Trimethyltin chloride; Phenylsuccinic acid; Crystal structures; Polymers; Chiral space group;
D O I：
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学科分类号：
摘要：
Two types of di- and trimethyltin(IV) polymers [(Me2Sn)4O2(C10H8O4)4]n1 and [(Me3Sn)2(C10H8O4)]n·DMF 2 have been synthesized by the reaction of trimethyltin chloride with (±)-phenylsuccinic acid under two different experimental conditions. Both of the complexes are characterized by elemental analysis, IR, NMR (1H, 13C, 119Sn) spectroscopy and X-ray crystallographic diffraction analysis. The structural analyses show that complex 1 is a two-dimensional corrugated sheet polymer consisting of dimeric tetraorganodistannoxane units and bridging ligands. Complex 2 is a 3D corrugated polymer in which the deprotoned acid occurs as a tetradentate ligand and is bonded by the four oxygen atoms. It is worth noting that the X-ray diffraction study reveals that complex 2 crystallizes in the orthorhombic space group P212121, which is chiral space group.
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页码：399 / 404
页数：5
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