Transformations of peroxide olefin ozonolysis products under the action of hydroxylamine and semicarbazide hydrochlorides in isopropyl alcohol

被引:0
作者
G. Yu. Ishmuratov
Yu. V. Legostaeva
L. R. Garifullina
L. P. Botsman
Z. I. Idrisova
R. R. Muslukhov
N. M. Ishmuratova
G. A. Tolstikov
机构
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center
[2] Russian Academy of Sciences,Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
来源
Russian Journal of Organic Chemistry | 2013年 / 49卷
关键词
Oxime; Ozonolysis; Ricinoleic Acid; Octanoic Acid; Hydroxylamine Hydrochloride;
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学科分类号
摘要
Hydroxylamine and semicarbazide hydrochlorides were shown to be efficient as reducing agents toward peroxide products of ozonolysis of various olefins with different degrees of substitution. The rate of the transformations aldehyde → aldehyde oxime → nitrile → ester upon treatment of peroxides with hydroxylamine hydrochloride in isopropyl alcohol was lower than in methanol.
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页码:1409 / 1414
页数:5
相关论文
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