Modular Analysis of the Crystal Structures of Sulfides and Sulfo Salts with Occupied Tetrahedra of Two Orientations

被引:0
作者
O. V. Frank-Kamenetskaya
机构
[1] St. Petersburg State University,
来源
Journal of Structural Chemistry | 2001年 / 42卷
关键词
Sulfur; Physical Chemistry; Sulfide; Crystal Structure; Inorganic Chemistry;
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学科分类号
摘要
As a result of modular analysis, relationships between the crystal structures of sulfides and sulfo salts □O[Tm, T′n ]S1-x (x = 0, 1/4) formed by close packing of sulfur atoms have been established. Four basic types of structure corresponding to the construction module of Laves polyhedra (framework, layer, chain, discrete polyhedron) have been revealed. Formation of superspacings ka, where a is the parameter of the commensurate crystal lattices of sphalerite and sulvanite, is analyzed.
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页码:956 / 966
页数:10
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