Synthesis of Tetraazide Derivatives of p-tert-Butylcalix[4]arene Using Copper-Catalyzed Nucleophilic Aromatic Substitution

被引：0
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作者：
G. A. Fatykhova
V. A. Burilov
M. N. Dokuchaeva
S. E. Solov’eva
I. S. Antipin
机构：
[1] Kazan Federal University,Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
[2] Russian Academy of Sciences,undefined
来源：
Doklady Chemistry | 2018年 / 479卷
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摘要：
Aromatic azido derivatives of p-tert-butylcalix[4]arene have been obtained for the first time using copper-catalyzed nucleophilic aromatic substitution of azide anion for bromide in 5,11,17,23-tetrabromo- 25,26,27,28-tetrabuthoxycalix[4]arene in a dioxane–water (3: 1) solvent mixture with N,N-dimethylethylenediamine as a stabilizing ligand for copper(I). When the reaction is carried out under with microwave heating, partial substitution products (mono-, distally di-, proximally di-, and trisubstituted) can be isolated in satisfactory yields.
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页码：64 / 67
页数：3
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