Photochemical reaction intermediates of benzyl chloride in condensed phase

被引：0
作者：
Hiroshi Hiratsuka
Takahiro Okamoto
Satoshi Kuroda
Tetsuo Okutsu
Hironori Maeoka
Mitsumasa Taguchi
Tetsutaro Yoshinaga
机构：
[1] Gunma University,Department of Chemistry
[2] Japan Atomic Energy Research Institute,Takasaki Radiation Chemistry Research Establishment
[3] Kyusyu Institute of Technology,Department of Chemistry
来源：
Research on Chemical Intermediates | 2001年 / 27卷
关键词：
Chloride; Physical Chemistry; Inorganic Chemistry; Acetonitrile; Cyclohexane;
D O I：
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学科分类号：
摘要：
Reaction intermediates produced upon the photolysis of benzyl chloride have been studied in glassy matrix and in solution. In the steady-state photolysis both benzyl radicals and structural isomers of benzyl chloride were formed in ethanol, while in 3-methylpentane the structural isomers were predominantly formed. The nanosecond laser photolyses of benzyl chloride in ethanol and in cyclohexane also generated benzyl radicals and structural isomers at room temperature. In acetonitrile, in addition to these species, benzyl cations were observed in the early stage after the photolysis.
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页码：137 / 153
页数：16
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