Electrochemical Properties of Nitride Phases in the Si3N4–Ca3N2and Si3N4–AlN–Ca3N2Systems

被引:0
作者
S. F. Pal'guev
R. P. Lesunova
E. I. Burmakin
E. S. Korovenkova
机构
[1] Russian Academy of Sciences,Institute of High
来源
Inorganic Materials | 2001年 / 37卷
关键词
Calcium; Aluminum; Silicon; Electrical Conductivity; Inorganic Chemistry;
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中图分类号
学科分类号
摘要
The electrical conductivity of silicon nitride and its solid solutions with calcium nitride and aluminum nitride was measured in the ranges 400–900 and 1000–1300°C. The conduction mechanisms were found to be substantially different in these temperature ranges. The Si3N4–Ca3N2solid solutions exhibited high ionic conductivity between 400 and 900°C. The densest and most oxidation-resistant materials were obtained in the Si3N4–AlN–Ca3N2system (Al introduced as fine powder and then nitrided).
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页码:684 / 687
页数:3
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