A microwave-assisted method for the rapid removal of K from phlogopite

被引：0
作者：
Stephen A. Stout
Sridhar Komarneni
机构：
[1] The Pennsylvania State University,Department of Crop and Soil Sciences and Materials Research Institute
来源：
Clays and Clay Minerals | 2002年 / 50卷
关键词：
Ion Exchange; K-depleted Phlogopite; Mica; Microwave; Radioactive Waste Disposal;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The ability to remove K rapidly with a solution containing sodium tetraphenylborate (NaTPB) from the interlayers of naturally-occurring phlogopite using a microwave-assisted technique has been examined. Samples were equilibrated with a 1.0 N sodium chloride (NaCl) — 0.2 N NaTPB — 0.01 M disodium ethylenediaminetetraacetic acid (EDTA) solution at 60, 80 and 100°C under both conventional and microwave-assisted heating methods and for periods of time ranging from 1 to 3 h. The samples also underwent treatments of either continuous time periods or for successive treatments of 1 h with a washing step between each treatment.
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页码：248 / 253
页数：5
相关论文
共 42 条
[1]  
Amphlett GB(1958)Synthetic ion exchange materials: I. Zirconium phosphate Journal of Inorganic and Nuclear Chemistry 6 220-235
[2]  
McDonald LA(1998)Ion exchange properties of the sodium phlogopite and biotite Solvent Extraction and Ion Exchange 16 1067-1090
[3]  
Redman MJ(1995)The cryptand [222] for exchanging cations of micas Clays and Clay Minerals 43 732-737
[4]  
Bortun AI(1998)Microwave techniques in the synthesis and modification of zeolite catalysts. A review Collection of Czechoslovak Chemical Communications 63 1699-1723
[5]  
Bortun LN(1999)DOE needs new waste separation technology Chemical & Engineering News 23 8-151
[6]  
Khainakov SA(1985)Phillipsite in Cs decontamination and immobilization Clays and Clay Minerals 33 145-708
[7]  
Clearfield A(1982)Use of γ-zirconium phosphate for Cs removal from radioactive waste Nature 299 707-198
[8]  
Bracke G(1982)Alternative radwaste solidification route for Three Mile Island wastes Journal of the American Ceramic Society 65 c-1288
[9]  
Satir M(1988)A cesium-selective ion sieve made by topotactic leaching of phlogopite mica Science 239 1286-1405
[10]  
Krauß P(1992)Microwave-hydrothermal synthesis of ceramic powders Materials Research Bulletin 27 1393-4010
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