Microwave-assisted oxidation of alcohols by hydrogen peroxide catalysed by tetrabutylammonium decatungstate

被引：0
|
作者：
Mateusz Galica
Wiktor Kasprzyk
Szczepan Bednarz
Dariusz Bogdał
机构：
[1] Cracow University of Technology,Chair of Biotechnology and Renewable Materials, Faculty of Chemical Engineering and Technology
来源：
Chemical Papers | 2013年 / 67卷
关键词：
oxidations; alcohols; hydrogen peroxide; polyoxymetalate; microwaves;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
This work deals with catalytic activity of tetrabutylammonium decatungstate(VI) in the oxidation of selected alcohols with hydrogen peroxide as an oxidant using 1,2-dichloroethane/water or acetonitrile/water as a solvent system. Different forms of heating were compared. The highest conversions of substrates were achieved in the two phase system acetonitrile/water using microwave irradiation combined with elevated pressure. Finally, optimum parameters for these reactions in a microwave pressurised reactor were established and discussed.
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页码：1240 / 1244
页数：4
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