Composition, structure, and properties of pharmacologically active silicon dimethylglycerolates

被引：0
|
作者：
T. G. Khonina
E. Yu. Larchenko
E. V. Shadrina
I. N. Ganebnykh
A. A. Boyko
E. G. Matochkina
M. I. Kodess
O. N. Chupakhin
机构：
[1] Ural Branch of the Russian Academy of Sciences,I. Ya. Postovsky Institute of Organic Synthesis
来源：
Russian Chemical Bulletin | 2010年 / 59卷
关键词：
organosilicon compounds; silicon dimethylglycerolates; composition; structure; viscosity; hydrolysis; condensation; H and ; Si NMR spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
1H and 29Si NMR spectroscopy showed that the product of the reaction of dimethyldiethoxysilane with glycerol in the molar ratio 1: 2 is an equilibrium mixture of dimethyldiglyceroxysilane and low-molecular-weight condensation products. The change of viscosity of silicon dimethylglycerolates, synthesized using different excesses of glycerol, versus time was studied by viscosimetry. Composition of products of hydrolysis and condensation of silicon dimethylglycerolates is determined by their concentration in the starting aqueous solutions.
引用
收藏
页码：2230 / 2235
页数：5
相关论文
共 50 条
  • [21] Influence of the Composition of a Boron-Containing Active Medium in the Form of a Coating on the Structure and Properties of the Diffusion Layer of Titanium Parts
    Guryev, A. M.
    Ivanov, S. G.
    Guryev, M. A.
    Deev, V. B.
    Loginova, M., V
    RUSSIAN JOURNAL OF NON-FERROUS METALS, 2022, 63 (02) : 184 - 189
  • [22] Influence of the Composition of a Boron-Containing Active Medium in the Form of a Coating on the Structure and Properties of the Diffusion Layer of Titanium Parts
    A. M. Guryev
    S. G. Ivanov
    M. A. Guryev
    V. B. Deev
    M. V. Loginova
    Russian Journal of Non-Ferrous Metals, 2022, 63 : 184 - 189
  • [23] EFFECT OF COMPOSITION AND HEAT TREATMENT ON THE STRUCTURE AND PROPERTIES OF CONDENSED COMPOSITES OF THE Cu - W SYSTEM
    Bukhanovskii, V. V.
    Minakova, R. V.
    Grechanyuk, I. N.
    Mamuzic, I.
    Rudnitskii, N. P.
    METAL SCIENCE AND HEAT TREATMENT, 2011, 53 (1-2) : 14 - 23
  • [24] Effect of composition and heat treatment on the structure and properties of condensed composites of the Cu – W system
    V. V. Bukhanovskii
    R. V. Minakova
    I. N. Grechanyuk
    I. Mamuziæ
    N. P. Rudnitskii
    Metal Science and Heat Treatment, 2011, 53 : 14 - 23
  • [25] Effect of composition on the properties of amorphous silicon carbide at a certain optical gap
    Shima, M
    Terakawa, A
    Isomura, M
    Tsuda, S
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1997, 36 (4A): : 2044 - 2048
  • [26] Composition, Structure, and Properties of Oxide-Salt Melts
    A. P. Osokin
    E. N. Potapova
    Glass and Ceramics, 2003, 60 : 296 - 301
  • [27] Composition, Structure, and Properties of Low-Fired Porcelain
    A. M. Eminov
    Z. R. Kadyrova
    Af. A. Eminov
    Yu. K. Zhumanov
    I. R. Boizhanov
    Glass and Ceramics, 2022, 79 : 135 - 138
  • [28] Composition, Structure, and Properties of Low-Fired Porcelain
    Eminov, A. M.
    Kadyrova, Z. R.
    Eminov, Af A.
    Zhumanov, Yu K.
    Boizhanov, I. R.
    GLASS AND CERAMICS, 2022, 79 (3-4) : 135 - 138
  • [29] Composition, structure, and properties of oxide-salt melts
    Osokin, AP
    Potapova, EN
    GLASS AND CERAMICS, 2003, 60 (9-10) : 296 - 301
  • [30] The composition, structure and properties of four different glassy carbons
    Shiell, Thomas B.
    Wong, Sherman
    Yang, Wenjie
    Tanner, Christopher A.
    Haberl, Bianca
    Elliman, Robert G.
    McKenzie, David R.
    McCulloch, Dougal G.
    Bradby, Jodie E.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2019, 522
12345