3-(1-Adamantyl)Furazans

被引：0
作者：
A. B. Sheremetev
A. M. Kozeev
N. S. Aleksandrova
M. I. Struchkova
K. Yu. Suponitsky
机构：
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
[2] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Chemistry of Heterocyclic Compounds | 2013年 / 49卷
关键词：
adamantanes; furazans; electrophilic reactions; X-ray structural analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reactivity of 3-(1-adamantyl)-4-aminofurazan was studied. Upon treatment with oxidizing reagents the amino group is oxidized to azo, azoxy, and nitro groups. The nitration of 3-(1-adamantyl)-4-aminofurazan with nitric acid provided the corresponding nitroamine. The reaction of 3-(1-adamantyl)-4-nitrofurazan with nitrating and bromination agents takes place at the bridgehead position of the adamantane fragment and gives the corresponding nitroxyl and bromo derivatives. An X-ray structural analysis of 4,4′-di(1-adamantyl)azofurazan was undertaken.
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页码：1358 / 1369
页数：11
相关论文
共 209 条
[1]  
Shvekhgeimer M.-G. A.(65)Propellants, Explos Usp. Khim. 65 603-undefined
[2]  
Litvinov V. P.(1997)undefined Zh. Org. Khim. 33 1447-undefined
[3]  
Shvekhgeimer M.-G. A.(1999)undefined Zh. Org. Khim. 35 183-undefined
[4]  
Shvekhgeimer M.-G. A.(2000)undefined Zh. Org. Khim. 36 329-undefined
[5]  
Litvinov V. P.(2010)undefined Curr. Med. Chem. 17 2967-undefined
[6]  
Litvinov V. P.(2011)undefined Eur. J. Med. Chem. 46 1949-undefined
[7]  
Shvekhgeimer M.-G. A.(1975)undefined Khim. Geterotsikl. Soedin. 11 32-undefined
[8]  
Lamoureux G(2007)undefined Eur. J. Med. Chem. 42 235-undefined
[9]  
Artavia G(2012)undefined ChemMedChem 7 920-undefined
[10]  
Liu J(1976)undefined J. Med. Chem. 19 1221-undefined
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