Synthesis and crystal structure of a supramolecular adduct of the cubane cluster [CIPdMo3Se4(H2O)7Cl2]+ with macrocyclic cavitand cucurbituril

被引：0
作者：
M. N. Sokolov
D. N. Dybtsev
A. V. Virovets
K. Hegetschweiler
V. P. Fedin
机构：
[1] Siberian Branch of the Russian Academy of Sciences,Institute of Inorganic Chemistry
[2] Universität des Saarlandes,Lehrstuhl für Anorganische Chemie
来源：
Russian Chemical Bulletin | 2000年 / 49卷
关键词：
selenide clusters; molybdenum; palladium; cucurbituril; X-ray diffraction analysis; supramolecular adduct;
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摘要：
A new heterometallic selenide-bridged 60-electron complex containing the cubane cluster fragment [M03(μ3-Se)4Pd]4τ was prepared by heating a solution of [Mo3Se4(H2O)9]Cl4 and palladium black in 2M HCl. The cluster complex was isolated from aqueous solutions as a hydrolytically stable supramolecular adduct with macrocyclic cavitand cucurbituril. The molecular and crystal structure of {[ClPdMo3Se4(H2O)7Cl2](C36H36N24O12)Cl}·7H2O were established by X-ray diffraction analysis.
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页码：1877 / 1881
页数：4
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