Characterization and use of activated carbon synthesized from sunflower seed shell in the removal of Pb(II), Cd(II), and Cr(III) ions from aqueous solution

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作者
Ibtihal A. Mawlood
Wahran M. Saod
Ahmed S. Al-Rawi
Abdulsalam M. Aljumialy
Nahla Hilal
机构
[1] University of Anbar,Department of Dams and Water Resources, College of Engineering
[2] University of Anbar,Department of Chemistry, College of Science
[3] University of Fallujah,Department of Applied Chemistry, College of Applied Science
[4] Scientific Affairs Department,undefined
[5] University Of Fallujah,undefined
来源
Environmental Monitoring and Assessment | 2024年 / 196卷
关键词
Adsorption; Heavy metals; Activated carbon; Isotherm;
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摘要
In this work, carbon-based nanomaterials such as active carbon which is prepared from common sunflower (Helianthus annuus) seed shell, and the characterization of the activated carbon NPs were studied using FTIR (Fourier transform infrared spectroscopy), XRD, SEM, EDS, and DTA techniques. Activated carbon NPs have been used in the adsorption of Pb(II), Cd(II), and Cr(III) ions from the aqueous phase. The results showed the highest adsorption efficiency was 99.9%, 92.45%, and 98% for Pb(II), Cd(II), and Cr(III) ions respectively at a temperature of 25 °C, pH = 7–9, and a time of 60 and 180 min, in addition to the accordance of the adsorption models for activated carbon with the Freundlich isotherm model at the value of R2 (0.9976, 0.9756, and 0.9907) and Langmuir isotherm model (0.966, 0.999, and 0.9873) of the Pb(II), Cd(II), and Cr(III) ions, respectively. We conclude the possibility of using activated carbon to have an extremely high sorption capacity across the conditions tested, with the highest adsorption efficiency having been >99% for Pb(II), Cd(II), and Cr(III) ions within the pH range 7–9 and a contact time of 60 to 180 min.
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