The electrical resistivity technique which involved the Schlumberger depth sounding method and geochemical analyses of water samples collected from boreholes was used to investigate the suitability of groundwater aquifers in Abi for drinking and irrigation purposes. Fifty randomly located electrical resistivity data were collected, modeled, and interpreted after calibration with lithologic logs. Ten borehole water samples were collected and analysed to determine anion, cation concentrations and some physical and chemical parameters, such as water colour, temperature, total dissolved solids, and electrical conductivity. The results show that the lithostratigraphy of the study area is composed of sands, sandstones (fractured, consolidated and loosed), siltstones, shales (compacted and fractured) of the Asu River Group, Eze-Aku Formation which comprises the aquifer units, and the Nkporo Shale Formation. The aquifer conduits are known to be rich in silicate minerals, and the groundwater samples in some locations show a significant amount of Ca2+, Mg2+, and Na+. These cations balanced the consumption of H+ during the hydrolytic alteration of silicate minerals. The geochemical analysis of groundwater samples revealed dominant calcium–magnesium–carbonate–bicarbonate water facies. Irrigation water quality parameters, such as sodium absorption ratio, percentage of sodium, and permeability index, were calculated based on the physico-chemical analyses. The groundwater quality was observed to be influenced by the interaction of some geologic processes but was classified to be good to excellent, indicating its suitability for domestic and irrigation purposes. © 2016, The Author(s).