Enthalpies of formation of phenylaminyl radicals

被引：0

作者：

Chernova E.M. ^{[1
]}

Orlov M.Y. ^{[1
]}

Turovtsev V.V. ^{[1
]}

Orlov Y.D. ^{[1
]}

机构：

[1] Tver State University, 33 ul. Zhelyabova, Tver

来源：

Russian Chemical Bulletin | 2021年 / 70卷 / 2期

关键词：

additive-group model; enthalpy of formation; free radicals; quantitative “structure—property” correlation; substituted diphenylaminyl radicals; substituted phenylaminyl radicals;

D O I：

10.1007/s11172-021-3089-3

中图分类号：

学科分类号：

摘要：

Enthalpies of formation (ΔfH∘) for 31 radicals of the series of substituted Ph-N∙H and Ph-N∙-Ph were determined for the first time. The calculations were based on the dissociation energies of N-H bonds in the corresponding molecules and their ΔfH∘. A quantitative “structure—enthalpy of formation” correlation was established for these radicals within the framework of the additive-group approach. The ΔfH∘ of radicals were analyzed and the most reliable values were suggested. © 2021, Springer Science+Business Media LLC.

引用

页码：330 / 335

页数：5

共 50 条

[1] Enthalpies of formation of phenylaminyl radicals
Chernova, E. M.
Orlov, M. Yu.
Turovtsev, V. V.
Orlov, Yu D.
RUSSIAN CHEMICAL BULLETIN, 2021, 70 (02) : 330 - 335
[2] Enthalpies of formation of alkyl radicals
Orlov, M. Yu.
Chernova, E. M.
Turovtsev, V. V.
Orlov, Yu. D.
RUSSIAN CHEMICAL BULLETIN, 2014, 63 (12) : 2620 - 2624
[3] Enthalpies of Formation of Acetyl Radicals
Orlov, Yu. D.
Chernova, E. M.
Orlov, M. Yu.
Turovtsev, V. V.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 87 (10) : 1607 - 1610
[4] Enthalpies of formation of acetyl radicals
Yu. D. Orlov
E. M. Chernova
M. Yu. Orlov
V. V. Turovtsev
Russian Journal of Physical Chemistry A, 2013, 87 : 1607 - 1610
[5] Enthalpies of formation of alkyl radicals
M. Yu. Orlov
E. M. Chernova
V. V. Turovtsev
Yu. D. Orlov
Russian Chemical Bulletin, 2014, 63 : 2620 - 2624
[6] Enthalpies of formation of amidyl free radicals
Yu. D. Orlov
V. V. Turovtsev
I. V. Stepnikov
A. N. Kizin
Yu. A. Lebedev
Russian Chemical Bulletin, 2004, 53 : 1635 - 1639
[7] Enthalpies of formation of amidyl free radicals
Orlov, YD
Turovtsev, VV
Stepnikov, IV
Kizin, AN
Lebedev, YA
RUSSIAN CHEMICAL BULLETIN, 2004, 53 (08) : 1635 - 1639
[8] Enthalpies of the formation of aliphatic carbonyl-containing radicals
Yu. D. Orlov
E. M. Chernova
V. V. Turovtsev
Russian Journal of Physical Chemistry A, 2012, 86 : 175 - 183
[9] Enthalpies of the formation of aliphatic carbonyl-containing radicals
Orlov, Yu. D.
Chernova, E. M.
Turovtsev, V. V.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 86 (02) : 175 - 183
[10] Enthalpies of formation of organic free radicals of alcohol and ether derivatives
Orlov, Yu. D.
Chernova, E. M.
Turovtsev, V. V.
RUSSIAN CHEMICAL BULLETIN, 2010, 59 (10) : 2009 - 2013

← 1 2 3 4 5 →