The corrosion inhibition of maraging steel under weld aged condition by 1(2E)-1-(4-aminophenyl)-3-(2-thienyl)prop-2-en-1-one in 1.5 M hydrochloric acid medium

被引:0
|
作者
B. S. Sanatkumar
Jagannath Nayak
A. Nityananda Shetty
机构
[1] National Institute of Technology Karnataka,Department of Chemistry
[2] National Institute of Technology Karnataka,Department of Metallurgical and Materials Engineering
来源
Journal of Coatings Technology and Research | 2012年 / 9卷
关键词
Maraging steel; ATPI; Corrosion rate; EIS; SEM;
D O I
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学科分类号
摘要
The influence of 1(2E)-1-(4-aminophenyl)-3-(2-thienyl)prop-2-en-1-one (ATPI) on the corrosion behavior of weld aged maraging steel in 1.5 M hydrochloric acid was studied by potentiodynamic polarization method and AC impedance (EIS) technique at different temperatures. The results showed that the inhibition efficiency of ATPI increased with the increase in the concentration of inhibitor and decreased with the increase in temperature. ATPI acts as a mixed type inhibitor without affecting the mechanism of the hydrogen evolution reaction or iron dissolution. The adsorption of ATPI on a weld aged maraging steel surface obeys the Langmuir adsorption isotherm equation. Both activation and thermodynamic parameters were calculated and discussed. ATPI inhibits the corrosion through both physisorption and chemisorption on the alloy surface. The surface morphology of the weld aged maraging steel specimens in the presence and the absence of the inhibitors was studied by the respective SEM images.
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页码:483 / 493
页数:10
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