Synthesis and oxidation of vinyl derivatives of N-methyl[60]fullereno[c]pyrrolidine

被引:0
|
作者
N. V. Abramova
A. G. Ginzburg
V. I. Sokolov
机构
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源
Russian Chemical Bulletin | 2010年 / 59卷
关键词
-methyl[60]fullereno[; ]pyrrolidine; chlorovinylcymantrene; chlorovinylferrocene; cymantrene; cyclopentadienylrhenium tricarbonyl; -oxides; 3-chloroperoxybenzoic acid; Prato reaction;
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摘要
Novel organometallic derivatives of N-methyl[60]fullereno[c]pyrrolidine bearing the vinyl fragment at the position 2 of the pyrrolidine ring were synthesized. Their oxidation with 3-chloroperoxybenzoic acid to give N-oxides and epoxides was studied in detail.
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页码:1964 / 1966
页数:2
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