Zinc N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate: Complexation and ion-selective properties

被引：0
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作者：
I. S. Ivanova
A. V. Dorokhov
E. N. Pyatova
A. S. Burlov
A. D. Garnovskii
A. Yu. Tsivadze
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Rostov State University,Institute of Physical and Organic Chemistry
[3] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry
来源：
Russian Journal of Inorganic Chemistry | 2007年 / 52卷
关键词：
Crown Ether; Alkali Metal Salt; Macrocyclic Ring; Neutral Carrier; Potentiometric Selectivity;
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摘要：
The lithium, sodium, and potassium complexes with zinc N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate (ZnL2) have been synthesized. Their IR spectra have been studied, and selected vibrational frequencies of the ligand and complexes have been assigned. Based on spectroscopy and elemental analysis data, the structure of the complexes has been suggested. The ion-selective properties of ZnL2 have been studied by potentiometry.
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页码：1704 / 1712
页数：8
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