New method for the preparation of solid polymer electrolyte based on poly(vinylidene fluoride-co-hexafluoropropylene)

被引：0
作者：
Taehee Kim
Ik Joong Kang
Gyoujin Cho
Kwon-pil Park
机构：
[1] Sunchon National University,Department of Chemical Engineering
[2] Kyungwon University,Department of Chemical and Bio Engineering
来源：
Korean Journal of Chemical Engineering | 2005年 / 22卷
关键词：
Solid Polymer Electrolyte; Gelation; Conductivity; Mechanical Strength; PVDF-HFP;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel solid polymer electrolyte (pore-gel SPE) has been found to provide superior SPE having a high conductivity, good mechanical strength and low solution leakage. This pore-gel SPE was prepared from gelation in pores of polymer membrane with electrolyte solution including solvent. The conductivity of pore-gel type PVDF-HFP/ TEABF4 (Tetraethylammomium tetrafluoroborate) membrane can reach 1.6×10-1 Scm-1. The tensile strength of this membrane was 4,000 kPa, which is about 23 times larger than that of gel-type SPE with the same composition. Poregel SPE reduced solution leakage to 0%, compared with 2% of hybrid-type SPE after 2.0 hr leakage test in PVDFHFP/ TEABF4 membrane.
引用
收藏
页码：234 / 237
页数：3
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