Electrochemical characterization of carbon paste electrodes modified with MgZnGa and ZnGaAl hydrotalcite-like compounds

被引：0
|
作者：
Vianney Aguilar-Vargas
Jaime S. Valente
Ignacio González
机构：
[1] Universidad Autónoma Metropolitana,Departamento de Química
[2] Instituto Mexicano del Petróleo,undefined
来源：
Journal of Solid State Electrochemistry | 2013年 / 17卷
关键词：
Hydrotalcites; Carbon paste electrodes; Electrocatalysis; Chronoamperometry; Voltammetry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two hydrotalcite-like compounds (HTs) were synthesized by coprecipitation. The electrochemical behavior of MgZnGa ([Mg0.58 Zn0.17Ga0.25 (OH)2] (CO3)2−0.125 1.5 H2O) and ZnGaAl ([Zn0.75Ga0.19 Al0.06 (OH)2] (CO3)2−0.125·1.5 H2O) Hydrotalcite-like compounds (HTs) was studied in NaOH at different concentrations. Voltammetric and chronoamperometric studies were performed to identify oxidation and reduction processes and the effect of the cations in total reactivity. Electrocatalytic effect of HTs on hydroxide electrochemical oxidation shows better performance of MgZnGa; this is apparently due to the presence of Mg and a greater amount of Ga3+ in the lattice of this HT. As far as reduction is concerned, Zn(II) reduction process is observed within the lattices of both HTs and is influenced by both the amount of OH− in the solution and the potential which the previous oxidation has been performed.
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页码：3145 / 3152
页数：7
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