Kinetics and Thermodynamics of the Mediator Function of 9,10-Anthraquinone Derivatives in Electrochemical Reactions with Peroxidase

被引：0

作者：

V. A. Shapovalov

机构：

[1] National Pharmaceutical Academy,

来源：

Russian Journal of General Chemistry | 2004年 / 74卷

关键词：

Electron Transfer; Quinone; Active Center; Thermodynamic Parameter; Electrochemical Reaction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

On the basis of the results of studying bioelectrocatalysis induced by electrochemical reductionof N-(9'10-anthraquinon-1-, -2-yl)oxamides under conditions close to physiological in the presence ofperoxidase, new criteria for estimation of the cholate-cholesterol coefficient of these compounds have beenproposed; these are the rate constants for homogeneous electron transfer from the reduced form of the quinone to the active center of peroxidase and thermodynamic parameters of the process.

引用

页码：368 / 370

页数：2