Effect of CH4/air ratio on selectivity of partial oxidation of methane on V2O5/SiO2 catalyst

被引：0
作者：
Bostan A.I. [1 ]
Pyatnitskii Yu.I. [1 ]
Raevskaya L.N. [1 ]
Borisenko M.V. [2 ]
Pryanikova V.G. [1 ]
机构：
[1] L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 03039 Kyiv
[2] Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 03164 Kyiv
来源：
Theoretical and Experimental Chemistry | 2002年 / 38卷 / 6期
关键词：
Catalyst; Conversion; Formaldehyde; Methane; Partial oxidation; Selectivity;
D O I：
10.1023/A:1022223703187
中图分类号：
学科分类号：
摘要：
We have studied partial oxidation of methane on V2O 5/SiO2 (0.8 mass % V) in a flow-through catalytic fixed-bed reactor. We found that the methane/air ratio in the starting reaction mixture has practically no effect on the selectivity of the process. The dependence of the selectivity on the methane conversion can be described by a model with such reaction parameters as the initial selectivity and the relative reactivity (with respect to methane) of the reaction products. ©2002 Plenum Publishing Corporation.
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页码：363 / 366
页数：3
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